2. Academic Validation
  3. Gold(III)-catalyzed nucleophilic substitution of propargylic alcohols

Gold(III)-catalyzed nucleophilic substitution of propargylic alcohols

  • J Am Chem Soc. 2005 Oct 19;127(41):14180-1. doi: 10.1021/ja0534147.
Marie Georgy 1,  Valérie Boucard,  Jean-Marc Campagne
Affiliations

Affiliation

  • 1 Institut de Chimie des Substances Naturelles, CNRS, Avenue de la Terrasse, F-91190 Gif-sur-Yvette, France.
PMID: 16218601 DOI: 10.1021/ja0534147
Abstract

Gold-catalyzed nucleophilic substitution on propargylic alcohols, with various C-, O-, and S-nucleophiles, is described under very mild conditions (room temperature, dichloromethane) in 0-97% yield.

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