2. Academic Validation
  3. Identification and characterisation of the phenolics of Ilex glabra L. Gray (Aquifoliaceae) leaves by liquid chromatography tandem mass spectrometry

Identification and characterisation of the phenolics of Ilex glabra L. Gray (Aquifoliaceae) leaves by liquid chromatography tandem mass spectrometry

  • Phytochemistry. 2014 Oct;106:141-155. doi: 10.1016/j.phytochem.2014.07.018.
Rakesh Jaiswal 1,  Elias A Halabi 2,  Mohamed Gamaleldin Elsadig Karar 2,  Nikolai Kuhnert 3
Affiliations

Affiliations

  • 1 School of Engineering and Science, Chemistry, Jacobs University Bremen, Campus Ring 1, 28759 Bremen, Germany. Electronic address: r.jaiswal@jacobs-university.de.
  • 2 School of Engineering and Science, Chemistry, Jacobs University Bremen, Campus Ring 1, 28759 Bremen, Germany.
  • 3 School of Engineering and Science, Chemistry, Jacobs University Bremen, Campus Ring 1, 28759 Bremen, Germany. Electronic address: n.kuhnert@jacobs-university.de.
PMID: 25086488 DOI: 10.1016/j.phytochem.2014.07.018
Abstract

The phenolics of the leaves of Ilex glabra L. Gray (Aquifoliaceae) were investigated qualitatively by LC-MS(n). Thirty-two phenolics were detected and characterised on the basis of their unique fragmentation pattern in the negative ion mode tandem MS spectra. All of them were extracted for the first time from this source and fifteen of them were not reported previously in nature. For the positive identification of phenolic glucosides by LC-MS(n) a series of authentic standards and experiments were carried out. This is the first report of a full characterisation of 3,4-dihydroxybenzoyl glucosides, 3,4-dihydroxybenzyl glucosides, 4-hydroxybenzoyl glucosides, chlorogenic acid glucosides and vanillic acid glucosides by LC-MS(2-4).

Keywords

(3,4-Dihydroxy)benzoates; 3,4-Dihydroxybenzoyl glucosides; 3,4-Dihydroxybenzyl glucosides; 4-Hydroxybenzoyl glucosides; Chlorogenic acid; Ilex glabra L. Gray; Polyphenols; Tandem MS.

Figures
Products
嗨！很高兴为您提供帮助！

尊敬的 MCE 客户您好，
请您选择所在区域，我们将转接对应客服为您服务！

热门区域

A

B

C

F

G

H

J

L

N

Q

S

T

X

Y

Z

热 A B C F G H J L N Q S T X Y Z