2. Academic Validation
  3. Aristolane-type Sesquiterpenoids from Nardostachys chinensis and Revised Structure of Aristolanhydride

Aristolane-type Sesquiterpenoids from Nardostachys chinensis and Revised Structure of Aristolanhydride

  • Nat Prod Bioprospect. 2019 Apr;9(2):149-155. doi: 10.1007/s13659-019-0200-7.
Li-Xia Wang 1 2,  Xian-Jun Jiang 1 2,  Xiang-Mei Li 1 2,  Mei-Fen Mao 1 2,  Guo-Zhu Wei 1 2,  Fei Wang 3 4
Affiliations

Affiliations

  • 1 BioBioPha Co., Ltd., Kunming, 650201, People's Republic of China.
  • 2 Reference Substances Sub-center, National Engineering Research Center for Modernization of Traditional Chinese Medicine, Kunming, 650201, People's Republic of China.
  • 3 BioBioPha Co., Ltd., Kunming, 650201, People's Republic of China. f.wang@mail.biobiopha.com.
  • 4 Reference Substances Sub-center, National Engineering Research Center for Modernization of Traditional Chinese Medicine, Kunming, 650201, People's Republic of China. f.wang@mail.biobiopha.com.
PMID: 30848431 DOI: 10.1007/s13659-019-0200-7
Abstract

Four hitherto unknown aristolane-type Sesquiterpenes, including one novel 8,9-secoaristolane, namely secoaristolenedioic acid (1), two aristolone derivatives, namely 1α,2β-dihydroxyaristolone (2), 9-epidebilon (3), and one rare aristolane-chalcone hybrid, namely 3'-hydroxynardoaristolone A (4) were isolated from the ethanol extract of the roots and rhizomes of Nardostachys chinensis. Their structures were elucidated on the basis of extensive spectroscopic analysis. In addition, the structure of aristolanhydride, recently isolated from the same species, was corrected by reanalysis of the published NMR data.

Keywords

Aristolane; Aristolane-chalcone hybrid; Nardostachys chinensis; Secoaristolane; Structural revision.

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