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  2. Diphenyl-1-pyrenylphosphine: photo-triggered AIE/ACQ transition with remarkable third-order nonlinear optical signal change

Diphenyl-1-pyrenylphosphine: photo-triggered AIE/ACQ transition with remarkable third-order nonlinear optical signal change

  • Chem Commun (Camb). 2020 Apr 14;56(30):4220-4223. doi: 10.1039/d0cc01031f.
Chang Xing 1 Jianxun Liu 1 Fang Chen 1 Yuanyuan Li 2 Changjian Lv 1 Qiuchen Peng 3 Hongwei Hou 1 Kai Li 1
Affiliations

Affiliations

  • 1 Green Catalysis Center, and College of Chemistry, Zhengzhou University, Henan 450001, P. R. China. likai@zzu.edu.cn.
  • 2 School of Chemistry and Chemical Engineering, Henan University of Technology, Henan 450001, P. R. China. yuanyuanli@haut.edu.cn.
  • 3 Green Catalysis Center, and College of Chemistry, Zhengzhou University, Henan 450001, P. R. China. likai@zzu.edu.cn and School of Chemistry and Chemical Engineering, Henan University of Technology, Henan 450001, P. R. China. yuanyuanli@haut.edu.cn.
Abstract

A propeller-like pyrene derivative of diphenyl-1-pyrenylphosphine (DPPP) is designed and synthesized. DPPP exhibits a unique photo-triggered AIE/ACQ transition with a remarkable third-order nonlinear optical signal change, which is proved to originate from the photo-induced oxidation of a phosphorus atom.

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